By E.G. Brame (Auth.)
Functions OF POLYMER SPECTROSCOPY
summary: functions OF POLYMER SPECTROSCOPY
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Extra resources for Applications of Polymer Spectroscopy
JOESTEN T. E. NOWLIN E. W. WISE RESEARCH AND DEVELOPMENT DEPARTMENT UNION CARBIDE CORPORATION BOUND BROOK, NEW JERSEY I. Introduction II. Experimental Technique III. Compositional Analysis and Sequence Distribution by Proton Magnetic Resonance (PMR) A. Ethylene-Ethyl Acrylate (EEA) Copolymer B. Ethylene-Ethyl Acrylate-Carbon Monoxide (E/EA/CO) Terpolymers C. Ethylene-2-Ethyl Hexyl Acrylate-Carbon Monoxide (E/2EHA/CO) Terpolymers IV. Analysis by Infrared V. Analysis by Differential Scanning Calorimetry (DSC) VI.
Part A-1 11, 233 (1973). 13. J. Schaefer and D. F. S. Natusch, Macromolecules 5, 416 (1972). 14. M. J. Roedel, / . Amer. Chem. Soc. 75, 6110 (1953). 15. J. C. Randall, / . Polym. Sei. Part A-2 11, 275 (1973). 16. D. E. Dorman, E. P. Otocka, and F. A. Bovey, Macromolecules 5, 574 (1972). 17. T. K. Wu, Macromolecules 2, 520 (1969); 3, 610 (1970). 18. K. J. Liu, J. Polym. Sei. Part A-2 4, 155 (1966); 5, 1209 (1967); 6, 947 (1968). 19. T. K. Wu, Macromolecules 6, 737 (1973). APPLICATIONS OF POLYMER SPECTROSCOPY 4 Instrumental Characterization of Ethylene-Ethyl Acrylate-Carbon Monoxide Terpolymers J.
Vinyl acetate, alkyl acrylates, carbon monoxide, and many other comonomers have been investigated [1,3]. Carbon monoxide is a particularly interesting comonomer . It is readily available, economical, and confers polarity and photodegrading [9-11], properties on polyethylene systems. The kinetics , mechanism , and morphology  of ethylenecarbon monoxide copolymers have been studied in detail. The resulting copolymers have a polyketonic structure of the type shown in (I), where n changes as a function of the monomer feed (CH 2 —CH 2 )„—(CO)— (I) composition.