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The rate of heterocoagulation was followed in dispersions of two kinds of particles of different sizes, present in various number concentration ratios, over a broad pH ¢, A R so " d,VR Fig. 8 ~-pojential as a function of the pH of Cr(OH)3 'xH20 (O, A, e, g ) and of polyvinyl chloride (PVC) latex (©, &, O, Q) at four different ionic strengths (K). ,~/nm Fig. I. I. Acid Blue 45 (e) and (f). The spectra refer to a constant amount of 1 mg sample per cm2 [25] Figure 6 illustrates two so prepared pigments [25], and Fig.

Kaspar Dr. K. Tauer ( ~ ) •I. Kiihn • H. Kaspar Max-Planck-Institut fiir Kolloidund Grenzflfichenforschung Kantstral3e 55 14513 Teltow-Seehof,FRG Some colloid-chemical features of emulsion polymerisation Abstract Emulsion polymerisation is of great technical and economical importance as well as a process with a lot of colloid chemical features. Two of these colloid features, namely particle nucleation and swelling of polymer particles with monomer, are considered in more detail. It is shown that the particle nucleation can be described with a model based on the classical nucleation theory.

Angaben des Statistischen Bundesamt der Bundesrepublik Deutschland, Berlin 3. Gilbert RG (1995) Emulsion Polymerization, Academic Press, London 4. Harkins WD (1947) J Am Chem Soc 69:1428-1444 5. Smith WV, Ewart RH (1948) J Chem Phys 16:592-599 6. Fitch RM, Tsai CH (1971) In:Fitch RM (ed) Polymer Colloids. Plenum, New York, pp 73-102 7. Lichti G, Gilbert RG, Napper DH (1983) J Pol Sci-Polym Chem 21:269-291 8. Adamson AW (1990) Physical Chemistry of Surfaces. John Wiley & Sons, Inc, New York, pp 364-378 9.

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